INVESTIGATION OF ELECTROCATALYTIC ACTIVITY OF SOME METALLIDES AND INTERMETALLIC COMPOUNDS IN HYDROGEN EVOLUTION REACTION AND DEVELOPMENT OF METHODS OF ITS INCREASE

Authors

  • A.B. Shein Perm State National Research University
  • V.I. Kichigin Perm State National Research University
  • V.V. Panteleeva Perm State National Research University

DOI:

Keywords:

silicide, germanide, intermetallic compound, hydrogen evolution reaction, electrocatalysis

Abstract

Electrocatalytic activity of some metallides and intermetallic compounds in a hydrogen evolution reaction in acidic and alkaline solutions has been investigated. Ways of increasing the activity of the investigated materials in the hydrogen evolution reaction have been elaborated. Diagnostic criteria applicable to the method of electrochemical impedance spectroscopy have been suggested, which allow determining the nature of the reaction steps of the hydrogen evolution reaction, the hydrogen adsorption isotherm type, and establishing the presence or absence of hydrogen absorption, determining the values of the rate constants of the reaction stages of evolution and absorption of hydrogen.

Supporting Agencies
Работа выполнена при финансовой поддержке РФФИ (грант № 14-03-96000).

Author Biographies

  • A.B. Shein, Perm State National Research University
    доктор химических наук, заведующий кафедрой физической химии химического факультета
  • V.I. Kichigin, Perm State National Research University
    кандидат химических наук, старший научный сотрудник кафедры физической химии химического факультета
  • V.V. Panteleeva, Perm State National Research University
    кандидат химических наук, старший преподаватель кафедры физической химии химического факультета

References

  1. Kichigin V.I., Shein A.B. Diagnostic criteria for hydrogen evolution mechanisms in electrochemical impedance spectroscopy // Electrochim. Acta. - 2014. - Vol. 138. - P. 325-333.
  2. Kichigin V.I., Shein A.B. Kinetics and mechanism of hydrogen evolution reaction on cobalt silicides in alkaline solutions // Electrochim. Acta. - 2015. - Vol. 164. - P. 260-266.
  3. Kichigin V.I., Shein A.B. Influence of hydrogen absorption on the potential dependence of the Faradaic impedance parameters of hydrogen evolution reaction // Electrochim. Acta. - 2016. - Vol. 201. - P. 233-239.
  4. Kuz’minyh M.M., Kostrov A.I., Panteleeva V.V., Sein A.B. Elektrohimiceskaa aktivnost’ digermanida zeleza v reakcii vydelenia vodoroda. I. Kislaa sreda // Kondensirovannye sredy i mezfaznye granicy. - 2015. - T. 17. - No 3. - S. 341-348.
  5. Kostrov A.I., Kuz’minyh M.M., Panteleeva V.V., Sein A.B. Elektrohimiceskaa aktivnost’ digermanida zeleza v reakcii vydelenia vodoroda. II. Selocnaa sreda // Kondensirovannye sredy i mezfaznye granicy. - 2015. - T. 17. - No 3. - S. 349-357.
  6. Kicigin V.I., Sein A.B., Samsutdinov A.S. Kinetika katodnogo vydelenia vodoroda na monosilicide zeleza v kislyh i selocnyh sredah // Kondensirovannye sredy i mezfaznye granicy. - 2016. - T. 18. - No 3. - S. 326-337.
  7. Sein A.B., Kicigin V.I. Kinetika katodnogo vydelenia vodoroda na CeCu2Ge2-elektrode v kislyh i selocnyh rastvorah // Vest. Perm. un-ta. Ser.: Himia. - 2014. - Vyp. 3(15). - S. 14-24.
  8. Kicigin V.I., Sein A.B. Kinetika katodnogo vydelenia vodoroda na CeCu2Ge2-elektrode v selocnom rastvore. Vlianie poverhnostnoj i ob"emnoj diffuzii atomarnogo vodoroda // Vest. Perm. un-ta. Ser.: Himia. - 2016. - Vyp. 3(23). - S. 6-19.

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Published

2017-09-05

Issue

No. 2 (2017)

Section

Research: theory and experiment

How to Cite

Shein, A. ., Kichigin, V. ., & Panteleeva, V. . (2017). INVESTIGATION OF ELECTROCATALYTIC ACTIVITY OF SOME METALLIDES AND INTERMETALLIC COMPOUNDS IN HYDROGEN EVOLUTION REACTION AND DEVELOPMENT OF METHODS OF ITS INCREASE. Perm Federal Research Centre Journal, 2, 96-100. https://journal.permsc.ru/index.php/pscj/article/view/PSCJ2017n2p14