SYNTHESIS OF FINE DISPERSIVE HIERARCHICALLY STRUCTURED FILLERS FOR THE CREATION OF TEXTURED SUPERHYDROPHOBIC SURFACES

Authors

  • V.A. Valtsifer Institute of Technical Chemistry UB RAS
  • I.I. Lebedeva Institute of Technical Chemistry UB RAS
  • A.S. Starostin Institute of Technical Chemistry UB RAS

DOI:

Keywords:

fine fillers, hierarchical structure, super-hydrophobicity, alumina, spherulite, textured surface, hydrothermal synthesis

Abstract

The methods have been proposed for synthesis of inorganic fillers with a hierarchical structure based on finely divided aluminum oxide to produce textured superhydrophobic surfaces. We have studied the effect of the prescription and process parameters on the morphology, texture properties, dispersibility and particle size distribution, as well as modality of the hierarchical structure. The mechanism of formation of hierarchical structures and the ways of its modification have also been examined. A technique for alumina spherulite water-repellency treatment has been proposed, the complex of physical and chemical research, aimed at studying the hydrophobic properties of the obtained fillers, the optimization of quantitative and fractional composition of the fine hydrophobized fillers in the polymer matrix has been carried out. The approaches to the production of composite materials to create textured superhydrophobic surfaces were couched.

Supporting Agencies
Работа выполнена при финансовой поддержке РФФИ и Правительства Пермского края (грант № 14-03-96009).

Author Biographies

  • V.A. Valtsifer, Institute of Technical Chemistry UB RAS
    доктор технических наук, заместитель директора по научной работе
  • I.I. Lebedeva, Institute of Technical Chemistry UB RAS
    младший научный сотрудник
  • A.S. Starostin, Institute of Technical Chemistry UB RAS
    младший научный сотрудник

References

  1. Bojnovic L.B., Emel’anenko A.M. Gidrofobnye materialy i pokrytia: principy sozdania, svojstva i primenenie // Uspehi himii. - 2008. - T. 77. - Vyp. 7. - S. 619-638.
  2. Erbil H.Y., Demirel A.L., Avci Y., Mert O. Transformation of a Simple Plastic into a Superhydrophobic Surface // Science. - 2003. - Vol. 299. - Is. 5611. - P. 1377-1380.
  3. Chiou N.-R., Lu C., Guan J. [et al.] Growth and alignment of polyaniline nanofibres with superhydrophobic, superhydrophilic and other properties // Nature Nanotechnology. - 2007. - Vol. 2. - Is. 6. - P. 354-357.
  4. Martines E., Seunarine K., Morgan H. [et al.] Superhydrophobicity and Superhydrophilicity of Regular Nanopatterns // Nano Letters. - 2005. - Vol. 5. - Is. 10. - P. 2097-2103.
  5. He B., Patankar N. A., Lee J. Multiple Equilibrium Droplet Shapes and Design Criterion for Rough Hydrophobic Surfaces // Langmuir. - 2003. - Vol. 19. - Is. 12. - P. 4999-5003.
  6. Wang M.-F., Raghunathan N., Ziaie B. A Nonlithographic Top-Down Electrochemical Approach for Creating Hierarchical (Micro-Nano) Superhydrophobic Silicon Surfaces // Langmuir. - 2007. - Vol. 23. - Is. 5. - P. 2300-2303.
  7. Zhang G., Wang D., Gu Z.-Z., Mohwald H. Fabrication of Superhydrophobic Surfaces from Binary Colloidal Assembly // Langmuir. - 2005. - Vol. 21. - Is. 20. - P. 9143-9148.
  8. Starostin A.S., Valtsifer V.A., Strelnikov V.N. [et al.] Robust technique allowing the manufacture of superoleophobic (omniphobic) metallic surfaces // Advanced Engineering Materials. - 2014. - Vol. 16. - No 9 - P. 1127-1132.
  9. Grynyov R.S., Bormashenko Ed., Whyman G. [et al.] Superoleophobic Surfaces Obtained via Hierarchical Metallic Meshes // Langmuir. - 2016. - Vol. 32. - Is. 17. - P. 4134-4140.

Published

2017-09-04

Issue

Section

Research: theory and experiment

How to Cite

Valtsifer, V. ., Lebedeva, I. ., & Starostin, A. . (2017). SYNTHESIS OF FINE DISPERSIVE HIERARCHICALLY STRUCTURED FILLERS FOR THE CREATION OF TEXTURED SUPERHYDROPHOBIC SURFACES. Perm Federal Research Centre Journal, 1, 27-31. https://journal.permsc.ru/index.php/pscj/article/view/PSCJ2017n1p4