A mathematical model of motion of polymer systems with nanoaggregates in  the  pore space of an oil reservoir

Authors

DOI:

https://doi.org/10.7242/1999-6691/2025.18.3.18

Keywords:

percolation-hydrodynamic model of two-phase filtration, relative phase permeabilities, displacement of oil by polymer solutions, hyperbranched nanoaggregates, classic polymer solutions, oil recovery factor

Abstract

A percolation-hydrodynamic model of the process of oil displacement by polymer solutions with nanoaggregates of various structures has been formulated and numerically implemented. The model allows taking into account the features of the pore space structure and the nature of the interaction of nanoaggregates with its surface during the filtration of the polymer solution. The possibility of achieving a higher oil recovery factor in the case of using polymers with hyperbranched nanomaterials compared to the classical polymer effect is shown. A cycle of laboratory studies was implemented to verify the results of theoretical calculations obtained using the model and compare them with the  experimental data. The oil displacement process was modeled in terms of the composite model of a reservoir element assembled from 10 standard core samples taken from one oil-bearing reservoir. Theoretical estimates are in qualitative agreement with the results of the laboratory experiments also conducted with a composite reservoir model, and their quantitative difference is due to the use of the rheological law for Newtonian fluids in the mathematical model. The experimental results showed that the studied polymers are characterized by a pseudoplastic flow regime,  therefore the effective viscosity of the polymer solution is higher than that assumed in the calculations. Based on the theoretical and experimental studies, it can be concluded that the  application of polymer systems containing hyperbranched nanoaggregates leads to a significant increase in the residual resistance factor, where the formation of a stable polymer structure significantly decreases a porous medium’s permeability in flooded channels. The percolation-hydrodynamic model presented in this paper allows for a more adequate consideration of the physicochemical processes that occur during polymer flooding of oil-saturated reservoirs.

Downloads

Download data is not yet available.

References

Zheltov, Yu. P. Razrabotka neftyanykh mestorozhdeniy. Moscow: Nedra, 1986. 332 p.

Zolotukhin A.B., Pyatibratov P.V., Nazarova L.N., Yazynina I.V., Shelyago E.V. EOR methods applicability evaluation. Proceedings of Gubkin University. 2016. No. 2. P. 58–70.

Silin M.A., Magadova L.A., Davletshina L.F., Poteshkina K.A., Gvelesiani I.A., Thomas A., Ivanis A.I. Application experience and major trends in polymer flooding technology worldwide. Territoriya "NEFTEGAS". 2021. No. 9/10. P. 46–52.

Saboorian-Jooybari H., Dejam M., Chen Z. Half-Century of Heavy Oil Polymer Flooding from Laboratory Core Floods to Pilot Tests and Field Applications. SPE Canada Heavy Oil Technical Conference, Calgary, Alberta, Canada. 2015. DOI: 10.2118/174402-MS

Kadet V.V., Vasiliev I.V. Use of Hyperbranched Nanocomplexes to Improve the Efficiency of Polymer Flooding. Theoretical Foundations of Chemical Engineering. 2023. Vol. 57, no. 6. P. 1385–1393. DOI: 10.1134/s0040579523050421

Shporta, E. Yu. Funktsional’nyye proizvodnyye oligomernykh fosfazenov i siloksanov [Functional Derivatives of Oligomeric Phosphazenes and Siloxanes]: PhD Dissertation. Moscow: D.I. Mendeleev University of Chemical Technology, 2014. 154 p.

Tereshchenko T.A. Synthesis and application of polyhedral oligosilsesquioxanes and spherosilicates. Polymer Science Series B. 2008. Vol. 50. P. 249–262. DOI: 10.1134/S1560090408090054

Levich V.G. Physicochemical hydrodynamics. Englewood Cliffs, 1959. 700 p.

Sinayskiy E.G. Gidrodinamika fiziko-khimicheskikh protsessov. Moscow: Nedra, 1997. 339 p.

Entov V.M., Polishchuk A.M. Role of sorption processes with the motion of polymer solutions in a porous medium. Fluid Dynamics. 1975. Vol. 10. P. 422–428. DOI: 10.1007/BF01015266

Entov V.M., Zak S.A., Chen-Sin E. Modeling the displacement of petroleum by a polymer solution. Journal of Engineering Physics. 1985. Vol. 48. P. 149–153. DOI: 10.1007/BF00871862

Entov V.M., Kerimov Z.A. Displacement of oil by an active solution with a nonmonotonic effect on the flow distribution function. Fluid Dynamics. 1986. Vol. 21. P. 64–70. DOI: 10.1007/BF01051102

Frank-Kamenetskii D.A. Diffusion and Heat Exchange in Chemical Kinetics. Princeton University Press, 1955. 574 p.

Venitsianov E.V., Rubinshtein R.N. Dinamika sorbtsii iz zhidkikh sred. Moscow: Nauka, 1983. 237 p.

Ryzhikov N.I. Eksperimental’noye issledovaniye dinamiki zakhvata chastits i izmeneniya pronitsayemosti pri fil’tratsii suspenzii cherez poristuyu sredu [Experimental Study of Particle Capture Dynamics and Permeability Change During Suspension Filtration Through a Porous Medium]: PhD thesis / Ryzhikov N. I. Moscow: Sadovsky Institute of Geosphere Dynamics, Russian Academy of Sciences, 2014. 150 p.

Khavkin, A. Ya. Matematicheskoye modelirovaniye fiziko-khimicheskikh tekhnologiy povysheniya nefteotdachi. Moscow: Gubkin University, 2021. 425 p.

Persova M.G., Soloveichik Y.G., Patrushev I.I., Ovchinnikova A.S. Numerical simulation of oil production using surfactant- polymer flooding. Izvestiya of Saratov University. Mathematics. Mechanics. Informatics. 2021. Vol. 21, no. 4. P. 544–558. DOI: 10.18500/1816-9791-2021-21-4-544-558

Kireev T.F., Bulgakova G.T., Khatmullin I.F. Modeling of polymer flooding using Voronoi grid. Computational Continuum Mechanics. 2018. Vol. 11. P. 15–24. DOI: 10.7242/1999-6691/2018.11.1.2

Ferreira V., Moreno R. Single-Phase Polymer Flow in Porous Media: Numerical Model for Experimental Planning and Analysis. Proceedings of the XXXVI Iberian Latin-American Congress on Computational Methods in Engineering Ney Augusto Dumont (Editor), ABMEC. 2015. DOI: 10.20906/CPS/CILAMCE2015-0450

Al-Hajri S., Mahmood S.M., Abdulelah H., Akbari S. An Overview on Polymer Retention in Porous Media. Energies. 2018. Vol. 11. 2751. DOI: 10.3390/en11102751

Basniev K.S., Kadet V.V., Kanevskaya R.D., Fomin A.V. Analiz effektivnosti novykh metodov i agentov polimernogo zavodneniya dlya povysheniya koeffitsiyenta nefteizvlecheniya. Moscow: Gubkin University, 1998

Kravchenko M.N., Kadet V.V., Yarysh V.V., Dieva N.N., Lishchuk A.N. Percolation approach to hydrodynamic modeling of flooding through active agents. SOCAR Proceedings. 2020. No. 1. P. 29–35. DOI: 10.5510/OGP20200100419

Kadet V.V. Perkolyatsionnyy analiz gidrodinamicheskikh i elektrokineticheskikh protsessov v poristykh sredakh. Moscow: INFRA-M Scientific Publishing Center, 2020. 256 p.

Kadet V. Percolation Analysis of Underground Hydromechanics Problems with Applications to Reservoir Engineering. Beau Bassin: LAP LAMBERT, 2021. 84 p.

tNavigator Technical Reference Manual. Version 24.4. Rock Flow Dynamics, 2025

MRST 2024a — The MATLAB Reservoir Simulation Toolbox. Version 2024a. SINTEF, 2024

OPM Flow Documentation. Open Porous Media Initiative, 2019

Soo H., Radke C.J. Flow of dilute, stable liquid and solid dispersions in underground porous media. AIChE Journal. 1985. Vol. 31, no. 11. P. 1926–1928. DOI: 10.1002/aic.690311120

Dmitriev N.M., Kadet V.V. Gidravlika i neftegazovaya gidromekhanika. Moscow: Gubkin University, 2016. 352 p.

Wennberg K.E., Sharma M.M. Determination of the Filtration Coefficient and the Transition Time for Water Injection Wells. Society of Petroleum Engineers. 1997. DOI: 10.2118/38181-MS

Iwasaki T. Some Notes on Sand Filtration. Journal AWWA. 1937. Vol. 29, no. 10. P. 1591–1597. DOI: 10.1002/j.1551- 8833.1937.tb14014.x

Gruesbeck C., Collins R.E. Entrainment and Deposition of Fine Particles in Porous Media. Society of Petroleum Engineers Journal. 1982. Vol. 22, no. 6. P. 847–856. DOI: 10.2118/8430-PA

De Gennes P.G. Scaling Concepts in Polymer Physics. Cornell University Press, 1979. 324 p.

Lysenko E.A., Efimova A.A., Chernov I.V., Litmanovich E.A. Metodicheskiye razrabotki k prakticheskim rabotam po rastvoram polimerov. Ch. 1, 2. Moscow: MSU, 2011

Rege S.D., Fogler H.S. A network model for deep bed filtration of solid particles and emulsion drops. AIChE Journal. 1988. Vol. 34, no. 11. P. 1761–1772. DOI: 10.1002/AIC.690341102

Bakirov E.A., Ermolkin V.I., Larin V.I., Maltseva A.K., Rozhkov E.L. Geologiya nefti i gaza. Moscow: Nedra, 1990. 240 p.

Basniev K.S., Dmitriev N.M., Rozenberg G.D. Neftegazovaya gidromekhanika. Moscow–Izhevsk: Institute of Computer Research, Gubkin University, 2005. 543 p.

Cherepanova N.A., Usoltsev A.V., Kochetov A.V. Studying Polymer Flooding Performance in Cenomanian Reservoirs of Highly Viscous Oil. Oil and Gas Exhibition. 2022. No. 6. P. 51–55. DOI: 10.24412/2076-6785-2022-6-51-55

Petrov I.V., Tyutyaev A.V., Dolzhikova I.S. Program development for experimental evaluation of oil reservoir alkaline-SAS floodind efficiency. Advances in current natural sciences. 2016. No. 11. P. 182–185.

Kadet V.V., Vasilev I.V., Tiutiaev A.V. Effectiveness of the use of nanoaggregates for polymer treatment in oil fields with hard-to- recover reserves. Nanosystems: Physics, Chemistry, Mathematics. 2025. Vol. 16, no. 1. P. 14–21. DOI: 10.17586/2220-8054- 2025-16-1-14-21

Published

2025-12-14

Issue

Section

Articles

How to Cite

Kadet, V. V., & Vasilev, I. V. (2025). A mathematical model of motion of polymer systems with nanoaggregates in  the  pore space of an oil reservoir. Computational Continuum Mechanics, 18(3), 249-263. https://doi.org/10.7242/1999-6691/2025.18.3.18