Effect of tetrabutylammonium salts of polyhydroxo-substituted derivatives of the closo-dodecaborate anion on thermal-oxidative aging of polyurethane elastomers

Authors

  • V. Yu. Senichev Institute of Technical Chemistry UB RAS
  • V.N. Strelnikov Institute of Technical Chemistry UB RAS
  • A.S. Kubasov Kurnakov Institute of General and Inorganic Chemistry
  • S.Z. Popovich Kurnakov Institute of General and Inorganic Chemistry
  • N.P. Simonenko Kurnakov Institute of General and Inorganic Chemistry
  • M.V. Perepada Institute of Technical Chemistry UB RAS
  • S.V. Eryshkanov Research Institute of Polymer Materials
  • M.A. Makarova Institute of Technical Chemistry UB RAS
  • E.V Pogoreltsev Institute of Technical Chemistry UB RAS
  • K.Yu. Zhizhin Kurnakov Institute of General and Inorganic Chemistry
  • N.T. Kuznetsov Kurnakov Institute of General and Inorganic Chemistry

DOI:

https://doi.org/10.7242/2658-705X/2026.2.9

Keywords:

polyurethane, elastomers, accelerated thermal aging, physico-mechanical properties, closo-dodecaborate anion derivatives

Abstract

This article presents data on thermal-oxidative aging of samples of cast polyurethane elastomer based on oligoesters with new boron-containing thermal closo-dodecaborate anionbased stabilizers in the temperature range from 90 to 120°C, including tensile strength and relative modulus. Methods for synthesizing anhydrous tetrabutylammonium salts of di-, tri-, and polyhydroxo-substituted derivatives of the closo-dodecaborate anion are presented. An analysis of changes in elastomer strength during aging under atmospheric conditions made it possible to evaluate the corresponding patterns of structural changes in the studied materials depending on the additive used. Tetrabutylammonium 1,7-dihydroxo-closo-dodecaborate has been proven to be the most effective heat stabilizer. The use of standard methods for numerically assessing changes in aging strength allowed us to obtain the calculated values of the service life for the studied materials in the temperature range up to 90°C.

Supporting Agencies
Работа выполнена в рамках Государственного задания Министерства науки и высшего образования Российской Федерации (тема № 124022200003-8) с использованием оборудования ЦКП «Исследования материалов и вещества» ПФИЦ УрО РАН.

References

Downloads

Published

2026-07-10

Issue

No. 2 (2026)

Section

Chemistry and material sciences

License

Copyright (c) 2026 Perm Federal Research Centre Journal

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

Senichev, V. Y., Strelnikov, V., Kubasov, A., Popovich, S., Simonenko, N., Perepada, M., Eryshkanov, S., Makarova, M., Pogoreltsev, E., Zhizhin, K., & Kuznetsov, N. (2026). Effect of tetrabutylammonium salts of polyhydroxo-substituted derivatives of the closo-dodecaborate anion on thermal-oxidative aging of polyurethane elastomers. Perm Federal Research Centre Journal, 2, 133-147. https://doi.org/10.7242/2658-705X/2026.2.9